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Chapter 27
Organic Chemistry
 
 
 
Movie
Title
 movie
Caption
 The concept of chirality is illustrated in this animation.
Notes
 A chiral object is not superimposable on its mirror image. A carbon atom with four different groups is chiral so it cannot be superimposed on its mirror image. Two chiral isomers are called enantiomers and are designated as either the R or the S isomer. Enantiomers have similar physical properties but behave differently in chiral environments. Many molecules have more than one chiral carbon atom.
Movie
Title
 movie
Caption
 The various types of isomerism are demonstrated in this animation.
Notes
 Isomers are compounds that have the same chemical formula but different structural formulas. Configurational (structural) isomers differ in the locations of bonds or groups in the molecule. Stereoisomers have the same groups of atoms bonded to each other but differ in the spatial arrangements of the atoms. Geometrical (cis-trans) isomers and optical isomers are stereoisomers.
Movie
Title
 movie
Caption
 Animation showing the design and operation of a polarimeter.
Notes
 Nonpolarized light has its electric vectors vibrating in all planes. A polarizer allows only light vibrating in a single plane to pass through it. An analyzer is used to determine if the polarized light has been rotated. An achiral solution has no effect on the plane of polarization of the light. A solution containing an excess of one enantiomer of a chiral substance causes rotation of the plane of polarization of the light.
Movie
Title
 p 1073-3
Caption
 Surfactant molecules form micelles in water and associate with oil droplets to remove them from clothing.
Notes
 Testing for unsaturated hydrocarbons with Bromine. A surfactant molecule has a hydrophobic (nonpolar) tail and a hydrophilic (polar) head. In water surfactants form micelles (clusters of surfactant molecules) in which the hydrophobic tails interact with each other in the middle and the hydrophobic heads interact with water on the surface. If an oil droplet is present the hydrophobic tail of the surfactant is embedded in the oil and the polar group is in contact with water.
27.0CO
Title
 p 1058-1
Caption
 Vanillin, an aldehyde, gives vanilla beans their characteristic odor.
Notes
 Vanillin, an aldehyde, gives vanilla beans their characteristic odor.
27.1a-h
Title
 p 1058-1a
Caption
 Representations of methane molecule
Notes
 structures
27.2
Title
 27-2
Caption
  
Notes
 The ethane molecule C2H6
27.2a-c
Title
 27-1
Caption
 chem structure and space filling molecule
Notes
 chem structure and space filling molecule
27.3
Title
 27-3
Caption
  
Notes
 The propane molecule, C3H8.
27.3.1UN
Title
 p 1060-1a
Caption
 each carbon atom has four bonds
Notes
 each carbon atom has four bonds
27.3.2UN
Title
 p 1061-1a
Caption
 structure is flipped from left to right
Notes
 structure is flipped from left to right
27.3.3UN
Title
 p 1061-1b
Caption
 complete the structure of this isomer by adding hydrogen atoms
Notes
 complete the structure of this isomer by adding hydrogen atoms
27.3.4UN
Title
 p 1061-1c
Caption
 a three-carbon chain with two one-carbon branches
Notes
 a three-carbon chain with two one-carbon branches
27.3.5UN
Title
 p 1061-1d
Caption
 line angle structures
Notes
 line angle structures
27.3.6UN
Title
 p 1061-1
Caption
  
Notes
 A Swiss stamp commemorating the 100th anniversary of an international congress in Geneva
27.3.7UNT01
Title
 table 27-1
Caption
 Table 27.1- some common alkyl groups
Notes
 Table- some common alkyl groups
27.3.8UN
Title
 p 1063-1
Caption
 2,2,4-trimethylpentane
Notes
 2,2,4-trimethylpentane
27.3.9UN
Title
 ?
Caption
 Pr. Ex. 27-2A
Notes
 ?
27.3.10UN
Title
 p 1063-1a
Caption
 attach a methyl group to the second C atom
Notes
 attach a methyl group to the second C atom
27.3.11UN
Title
 p 1063-1b
Caption
 attach a t-butyl group to the fourth C atom
Notes
 attach a t-butyl group to the fourth C atom
27.3.12UN
Title
 p 1064-1
Caption
 add the remaining hydrogen atoms to give each carbon atom four bonds
Notes
 add the remaining hydrogen atoms to give each carbon atom four bonds
27.3.13UN
Title
 p 1064-1a
Caption
 1-bromopentane/2-bromopentane/3-bromopentane
Notes
 1-bromopentane/2-bromopentane/3-bromopentane
27.3.14UN
Title
 p 1064-1b
Caption
 carbon and oxygen with double bond
Notes
 carbon and oxygen with double bond
27.3.15UNT02
Title
 table 27.2
Caption
 Table 27-2-classes of organic compounds and their functional groups
Notes
 Table classes of organic compounds and their functional groups
27.4
Title
 27-4
Caption
 conformation models
Notes
 conformation models
27.4.1UN
Title
 p 1067-1
Caption
 cyclopropane, cyclobutane, cyclopentane, cyclohexane
Notes
 cyclopropane, cyclobutane, cyclopentane, cyclohexane
27.4.2UN
Title
 p 1067-1a
Caption
 line-angle representations
Notes
 line-angle representations
27.5
Title
 27-5
Caption
 bond angles in cyclopropane
Notes
 bond angles in cyclopropane
27.6
Title
 27-6
Caption
  
Notes
 Two important conformations of cyclohexane.
27.6.1UN
Title
 p 1068-1
Caption
 sodium carbonate minus one carbon
Notes
 sodium carbonate minus one carbon
27.6.2UN
Title
 p 1070-1
Caption
  
Notes
 A catalytic cracking unit (ñcat crackerî) at a petroleum refinery.
27.6.3UN
Title
 p 1070-1a
Caption
 2,2,4-trimethylpentane, n-heptane
Notes
 2,2,4-trimethylpentane, n-heptane
27.6.4UN
Title
 p 1070-1b
Caption
 ethene, 1-butene, 2-ethyl-1-pentene, ethyne, 1-butyne, 4-methyl-2-pentyne
Notes
 ethene, 1-butene, 2-ethyl-1-pentene, ethyne, 1-butyne, 4-methyl-2-pentyne
27.6.5UN
Title
 p 1071-1
Caption
 cis-2-butene, trans-2-butene
Notes
 cis-2-butene, trans-2-butene
27.7
Title
 27-7
Caption
  
Notes
 Geometric isomerism in 2-butene. (a) Ball-and-stick models. (b) Space-filling models.
27.7.1UN
Title
 p 1072-1a
Caption
 H2O is eliminated in the following reaction
Notes
 H2O is eliminated in the following reaction
27.7.2UN
Title
 p 1073-1
Caption
  
Notes
 Cutting steel with an oxyacetylene torch.
27.7.3UN
Title
 p 1073-1a
Caption
 two Br atoms are identical, as are the two OCH2 groups. Br2 and CH2PCH2 are known as symmetrical reactants
Notes
 two Br atoms are identical, as are the two OCH2 groups. Br2 and CH2PCH2 are known as symmetrical reactants
27.7.4UN
Title
 p 1073-1b
Caption
 HBr is a polar molecule with its positive end at the H atom and its negative end at the Br atom, 2-bromopropane is the sole product of this reaction
Notes
 HBr is a polar molecule with its positive end at the H atom and its negative end at the Br atom, 2-bromopropane is the sole product of this reaction
27.7.5UN
Title
 p 1073-1c
Caption
 reversible reaction, the addition reaction is favored in dilute acid, and the elimination reaction is favored in concentrated H2SO4(aq)
Notes
 reversible reaction, the addition reaction is favored in dilute acid, and the elimination reaction is favored in concentrated H2SO4(aq)
27.7.6UN
Title
 p 1074-1a
Caption
 addition reaction of alkynes
Notes
 addition reaction of alkynes
27.7.7UN
Title
 p 1074-1b
Caption
 2-pentyne, cis-2-pentene
Notes
 cis alkene
27.7.8UN
Title
 p 1074-1c
Caption
 2-pentyne, trans-2-pentene
Notes
 trans alkene
27.7.9UN
Title
 p 1074-1d
Caption
 Kekule structures
Notes
 benzene molecule
27.7.10UN
Title
 p 1075-1
Caption
  
Notes
 August Kekul_ (1829_1896)
27.7.11UN
Title
 p 1075-1a
Caption
 toluene, o-xylene, naphthalene, anthracene
Notes
 toluene, o-xylene, naphthalene, anthracene
27.7.12UN
Title
 p 1075-1b
Caption
 hexatriene, cyclopentadiene
Notes
 hexatriene, cyclopentadiene
27.7.13UN
Title
 p 1076-1a
Caption
 phenyl group, biphenyl, phenylhydrazine
Notes
 phenyl group, biphenyl, phenylhydrazine
27.7.14UN
Title
 p 1076-1b
Caption
 3-bromotoluene, 2-bromochlorobenzene, 1,4-dichlorobenzene, 2-chlorotoluene
Notes
 3-bromotoluene, 2-bromochlorobenzene, 1,4-dichlorobenzene, 2-chlorotoluene
27.7.15UN
Title
 p 1077-1a
Caption
 there are two possibilities for substitution that lead to an ortho isomer and two that lead to a meta isomer, however, we should expect the distribution of products to be 40% ortho, 40% meta, and 20% para
Notes
 there are two possibilities for substitution that lead to an ortho isomer and two that lead to a meta isomer, however, we should expect the distribution of products to be 40% ortho, 40% meta, and 20% para
27.7.16UN
Title
 p 1077-1b
Caption
 The Cl group, on the other hand, is an ortho,para director. Essentially no meta isomer is produced in reaction
Notes
 The Cl group, on the other hand, is an ortho,para director. Essentially no meta isomer is produced in reaction
27.7.17UN
Title
 p 1078-1a
Caption
 Predict the products of the mononitration
Notes
 Predict the products of the mononitration
27.7.18UN
Title
 p 1078-1b
Caption
 2,6-dinitrophenol, 2,4-dinitrophenol
Notes
 2,6-dinitrophenol, 2,4-dinitrophenol
27.7.19UN
Title
 p 1078-1c
Caption
 1-butanol, 2-butanol, 2-methyl-2-propanol
Notes
 1-butanol, 2-butanol, 2-methyl-2-propanol
27.7.20UN
Title
 p 1078-1d
Caption
 phenol, 2,4,6-trinitrophenol
Notes
 phenol, 2,4,6-trinitrophenol
27.7.21UN
Title
 p 1079-1a
Caption
 1,2-ethanediol, 1,2,3-propanetriol
Notes
 1,2-ethanediol, 1,2,3-propanetriol
27.7.22UN
Title
 p 1079-1b
Caption
  
Notes
 Giant soap bubble.
27.7.23UN
Title
 p 1079-1c
Caption
 propene, 2-propanol
Notes
 propene, 2-propanol
27.7.24UN
Title
 p 1080-1a
Caption
 diemthyl ether, diphenyl ether, methyl phenyl ether (anisole)
Notes
 diemthyl ether, diphenyl ether, methyl phenyl ether (anisole)
27.7.25UN
Title
 p 1080-1b
Caption
  
Notes
 This molecule should be named t-butyl methyl ether (TBME), but has been referred to by industrial chemists as MTBE for so long that it has become the commonly used name for this compound.
27.7.26UN
Title
 p 1080-1c
Caption
 Aldehydes and ketones contain the carbonyl group
Notes
 Aldehydes and ketones contain the carbonyl group
27.7.27UN
Title
 p 1080-1d
Caption
 methanal, 3-chlorobutanal, benzaldehyde, propanone, 3-pentanone, 1-phenylethanone
Notes
 methanal, 3-chlorobutanal, benzaldehyde, propanone, 3-pentanone, 1-phenylethanone
27.7.32UN
Title
 P 1082-1b
Caption
 False-color scanning electron micrograph of the sticky surface of a 3M Post-It note. The bubbles are 15-40 µm in diameter and consist of a urea-formaldehyde adhesive. Each time the note is pressed to a surface, fresh adhesive is released. The note can be reattached to a surface as long as some of the bubbles remain.
Notes
 False-color scanning electron micrograph of the sticky surface of a 3M Post-It note. The bubbles are 15_40 µm in diameter and consist of a urea_formaldehyde adhesive. Each time the note is pressed to a surface, fresh adhesive is released. T
27.7.28UN
Title
 p 1081-1a
Caption
 3-chloro-2-methylbutanal
Notes
 3-chloro-2-methylbutanal
27.7.29UN
Title
 p 1081-1b
Caption
 4-chloro-3-methyl-2-pentanone
Notes
 4-chloro-3-methyl-2-pentanone
27.7.30UN
Title
 p 1081-1c
Caption
 2-propanol, acetone
Notes
 ethanol, acetaldehyde, acetic acid, 2-propanol, acetone
27.7.31UN
Title
 P 1082-1a
Caption
 benzaldehyde, cinnamaldehyde, camphor
Notes
 benzaldehyde, cinnamaldehyde, camphor
27.7.33UN
Title
 P 1082-1c
Caption
 ketone reduced to secondary alcohol
Notes
 ketone reduced to secondary alcohol
27.7.34UN
Title
 P 1082-1d
Caption
 cyanohydrin
Notes
 cyanohydrin
27.7.35UN
Title
 p 1082-1e
Caption
 Compounds that contain the carboxyl group (carbonyl and hydroxyl) are called carboxylic acids
Notes
 Compounds that contain the carboxyl group (carbonyl and hydroxyl) are called carboxylic acids
27.7.36UN
Title
 p 1083-1a
Caption
 acetic acid, benzoic acid, oxalic acid, phthalic acid
Notes
 acetic acid, benzoic acid, oxalic acid, phthalic acid
27.7.37UN
Title
 p 1083-1b
Caption
 3-chlorobutanoic acid, 3-methylbenzoic acid, 2-hydroxybenzoic acid
Notes
 3-chlorobutanoic acid, 3-methylbenzoic acid, 2-hydroxybenzoic acid
27.7.39UN
Title
 p 1083-1d
Caption
 the remaining portion of the molecule
Notes
 the remaining portion of the molecule
27.7.40UN
Title
 p 1083-1e
Caption
 the acetyl group
Notes
 the acetyl group
27.7.41UN
Title
 p 1083-1f
Caption
 acetylsalicilic acid (aspirin)
Notes
 acetylsalicilic acid (aspirin)
27.7.42UN
Title
 p 1084-1
Caption
 ethanol, ethanoic acid, ethyl ethanoate
Notes
 ethanol, ethanoic acid, ethyl ethanoate
27.7.38UN
Title
 p 1083-1c
Caption
  
Notes
 The distinctive aroma and flavor of oranges are due in part to the ester octyl acetate, CH3(CH2)6CH2OOCCH3.
27.7.43UN
Title
 p 1085-1a
Caption
 nitrile group
Notes
 nitrile group
27.7.44UN
Title
 p 1085-1b
Caption
 resonance structure
Notes
 resonance structure
27.7.45UN
Title
 p 1085-1c
Caption
 reduction of methyl propionate
Notes
 reduction of methyl propionate
27.7.46UN
Title
 p 1085-1d
Caption
 ethyl amine
Notes
 ethyl amine
27.7.47UN
Title
 p 1086-1a
Caption
 ethylamine, diphenylamine, ethylmethylpropylamine
Notes
 ethylamine, diphenylamine, ethylmethylpropylamine
27.7.48UN
Title
 p 1086-1b
Caption
 reduction of a nitro compound
Notes
 reduction of a nitro compound
27.7.49UN
Title
 p 1086-1c
Caption
 dimethylamine
Notes
 dimethylamine
27.7.50UN
Title
 p 1086-1d
Caption
 methylamine, aniline
Notes
 methylamine, aniline
27.7.51UN
Title
 p 1087-1a
Caption
 an ammonium and N-methyl acetamide
Notes
 an ammonium and N-methyl acetamide
27.7.52UN
Title
 p 1087-1b
Caption
 tylenol
Notes
 tylenol
27.7.53UN
Title
 p 1087-1c
Caption
 quaternary ammonium salts
Notes
 quaternary ammonium salts
27.7.54UN
Title
 p 1087-1d
Caption
 Acetylcholine
Notes
 tetramethylammonium iodide
27.8
Title
 27-8
Caption
 Pyridine. In the pyridine molecule a nitrogen atom replaces one of the C-H units in benzene. Its formula is C5H5N. (a) Structural formula. (b) Space-filling model.
Notes
 Pyridine. In the pyridine molecule a nitrogen atom replaces one of the C„H units in benzene. Its formula is C5H5N. (a) Structural formula. (b) Space-filling model.
27.9.1UN
Title
 p 1088-1a
Caption
 chiral and achiral structures
Notes
 chiral and achiral structures
27.9
Title
 p 1088-1b?
Caption
 3-methylhexane
Notes
 chirality
27.9.2UN
Title
 ?
Caption
 chiral structures
Notes
 chiral structures
27.10
Title
 27-10?
Caption
 naming enantiomers
Notes
 naming enantiomers
27.9.3UN
Title
 p 1089-1a
Caption
 enantiomers of 2-chlorobutane
Notes
 enantiomers
27.10.1UN
Title
 p 1090-1c
Caption
 enantiometer of 1-choloto-1-iodoethane
Notes
 enantiometer of 1-choloto-1-iodoethane
27.10.2UN
Title
 p 1090-1b
Caption
 priority of atoms
Notes
 priority of atoms
27.10.3UN
Title
 p 1090-1a
Caption
 first point of difference in a chain determines priority
Notes
 first point of difference in a chain determines priority
27.10.4UN
Title
 p 1091-1a
Caption
 double and triple bonds
Notes
 double and triple bonds
27.10.5UN
Title
 p 1091-1b
Caption
 atoms shown in red show priority
Notes
 atoms shown in red show priority
27.10.6UNa-b
Title
 p 1092-1a
Caption
 assignment of priorities and configuration of a chiral center
Notes
 assignment of priorities and configuration of a chiral center
27.10.7UN
Title
 p 1092-1b
Caption
 ranking of an etyle group relative to the propyl group
Notes
 ranking of an etyle group relative to the propyl group
27.10.8UN
Title
 p 1092-1c
Caption
 viewing a molecule toward lowest priority H-atom
Notes
 viewing a molecule toward lowest priority H-atom
27.10.9UN
Title
 p 1092-1d
Caption
 ranking bromoethyl group relative to methyl group
Notes
 ranking bromoethyl group relative to methyl group
27.10.10UN
Title
 p 1092-1e
Caption
 (R)-4-bromo-2-butanol
Notes
 (R)-4-bromo-2-butanol
27.10.11UN
Title
 p 1092-1f
Caption
 bonding with a dashed line
Notes
 bonding with a dashed line
27.10.12UN
Title
 p 1093-1a
Caption
 lowest priority
Notes
 lowest priority
27.10.13UNa-c
Title
 p 1093-1b
Caption
 r configuration or s configuration
Notes
 r configuration or s configuration
27.10.14UNa-c
Title
 p 1093-1c
Caption
 identical molecules or enantiomers
Notes
 identical molecules or enantiomers
27.10.15UN
Title
 p 1093-1d
Caption
 1-chloro-1,2-difluoroethene
Notes
 1-chloro-1,2-difluoroethene
27.10.16UN
Title
 p 1094-1c
Caption
 E-stereoisomer
Notes
 E-stereoisomer
27.10.17UN
Title
 p 1094-1b
Caption
 E and Z stereoisomers of 1-chloro-1,2-difluoroethane
Notes
 E and Z stereoisomers
27.10.18UNa-b
Title
 p 1094-1a
Caption
 configurations of alkenes
Notes
 configurations of alkenes
27.10.19UNa-d
Title
 p 1095-1a
Caption
 assigning configuration
Notes
 assigning configuration
27.10.20UNa-d
Title
 p 1095-1b
Caption
 labeling E and Z isomers
Notes
 labeling E and Z isomers
27.10.21UN
Title
 p 1095-1c
Caption
 nucleophilic subsitution reaction
Notes
 nucleophilic subsitution reaction
27.10.22UN
Title
 p 1096-1
Caption
 formation of alkyl ammonium salts
Notes
 formation of alkyl ammonium salts
27.10.23UN
Title
 p 1097-1a
Caption
 Lewis structure of the methoxide ion
Notes
 Lewis structure of the methoxide ion
27.10.24UN
Title
 p 1097-1b
Caption
 Lewis structure of methanool
Notes
 Lewis structure of methanool
27.10.25UN
Title
 p 1097-1c
Caption
 Lewis structure of chloroethane
Notes
 Lewis structure of chloroethane
27.10.26UN
Title
 p 1097-1d
Caption
 Lewis structure of methanamine
Notes
 Lewis structure of methanamine
27.10.27UN
Title
 p 1097-1e
Caption
 electrophiles vs. nucleophiles-Pr. Ex. 27-8A
Notes
 electrophiles vs. nucleophiles
27.10.28UN
Title
 p 1098-1
Caption
 concerted step
Notes
 concerted step
27.11
Title
 27-11
Caption
 transition state formed by HO ion and chloromethane
Notes
 transition state formed by HO ion and chloromethane
27.12
Title
 27-12
Caption
 formation of the transition state
Notes
 formation of the transition state
27.12.1UN
Title
 p 1099-1a
Caption
 a bromide atom and a carbocation
Notes
 a bromide atom and a carbocation
27.12.2UN
Title
 p 1099-1b
Caption
 planar carbocation reacts with the nucleophile
Notes
 planar carbocation reacts with the nucleophile
27.12.3UN
Title
 p 1099-1c
Caption
 neutral alcohol and a hydronium ion
Notes
 neutral alcohol and a hydronium ion
27.13
Title
 27-13
Caption
 the reaction profile for SN1
Notes
 the reaction profile for SN1
27.14.1UN
Title
 27-14
Caption
 a racemic mixture
Notes
 a racemic mixture
27.14
Title
 27-14
Caption
 a 50:50 mixture of product enantiomers
Notes
 a 50:50 mixture of product enantiomers
27.14.2UN
Title
 p 1101-1a
Caption
 decrease in rates
Notes
 decrease in rates
27.15a-e
Title
 27-15
Caption
 space filling models
Notes
 space filling models
27.15.1UN
Title
 p 1102-1a
Caption
 acetone reaction
Notes
 acetone reaction
27.16
Title
 27-16
Caption
 reactions
Notes
 reactions
27.16.1UN
Title
 p 1105-1
Caption
  
Notes
 Extruding polyethylene film.
27.16.3UNT05
Title
 table 27.5
Caption
 table - some polymers produced by a chain reaction polymerization
Notes
 table - some polymers produced by a chain reaction polymerization
27.16.2UN
Title
 p 1106-1
Caption
 terephthalic acid, ethylene glycol, poly(ethylene glycol terephthalate) (Dacron)
Notes
 terephthalic acid, ethylene glycol, poly(ethylene glycol terephthalate) (Dacron)
27.16.5UN
Title
 p 1106-1a
Caption
 the usual designation of a polymer, when applied to polypropylene
Notes
 the usual designation of a polymer, when applied to polypropylene
27.16.4UNT06
Title
 table 27.6
Caption
 table- some polymers produced by step reaction polymerization
Notes
 table- some polymers produced by step reaction polymerization
27.17
Title
 27-17
Caption
  
Notes
 Three representations of a polypropylene chain.
27.17.1UN
Title
 p 1108-1
Caption
  
Notes
 The synthesis from coal tar chemicals of the purple dye mauveine by William Perkin marked the beginning of the synthetic dye industry.
27.17.2UN
Title
 p 1108-1a
Caption
 Tyrian purple
Notes
 Tyrian purple
27.17.3UN
Title
 p 1108-1b
Caption
 indigo
Notes
 indigo
27.17.4UN
Title
 Beta-carotene
Caption
 Beta-carotene
Notes
 indigo
27.17.5UN
Title
 p 1109-1a
Caption
 the carbonyl group
Notes
 the carbonyl group
27.17.6UN
Title
 p 1109-1b
Caption
 the carboxyl group
Notes
 the carboxyl group
27.17.7UN
Title
 p 1109-1c
Caption
 structure of spodoptol
Notes
 structure of spodoptol
27.17.8UN
Title
 p 1110-1a
Caption
 Lindlar's catalyst
Notes
 Lindlar's catalyst
27.17.9UN
Title
 ??
Caption
 Lindlar's catalyst
Notes
 Lindlar's catalyst
27.17.10UN
Title
 p 1111-1a
Caption
 Review Question 1c
Notes
 benzene hexagonal structure
27.17.11UNd-f
Title
 p 1111-1b
Caption
 Review Question 10d-isomer or not?
Notes
 isomer or not?
27.17.12UNa-c
Title
 p 1111-1c
Caption
 Review Question 11
Notes
 give an acceptable name for the following:
27.17.13UNa-c
Title
 p 1111-1d
Caption
 Review Question 12
Notes
 give an acceptable name for the following:
27.17.14UNa-c
Title
 p 1112-1a
Caption
 Review Question 21
Notes
 identifying reactions
27.17.15UNa-c
Title
 p 1112-1b
Caption
 Review Question 22
Notes
 identifying reactions
27.17.16UNa-b
Title
 p 1112-1c
Caption
 Ex. 26-represent chemical bonding in terms of the overlap of hybridized and unhybridized atomic orbitals in the following molecules
Notes
 represent chemical bonding in terms of the overlap of hybridized and unhybridized atomic orbitals in the following molecules
27.17.17UN
Title
 p 1112-1d
Caption
 Ex. 27c-what term best describes the following pairs of isomers?
Notes
 what term best describes the following pairs of isomers?
27.17.18UN
Title
 p 1112-1e
Caption
 Ex. 28c
Notes
 structures
27.17.19UNa-c
Title
 p 1113-1a
Caption
 Ex. 31-identifying chiral carbon atoms
Notes
 identifying chiral carbon atoms
27.17.20UNa-c
Title
 p 1113-1b
Caption
 Ex. 32-identifying chiral carbon atoms
Notes
 identifying chiral carbon atoms
27.17.21UNa-c
Title
 p 1113-1c
Caption
 Ex. 33-identifying chiral carbon atoms
Notes
 identifying chiral carbon atoms
27.17.22UNa-c
Title
 p 1113-1d
Caption
 Ex. 34-identifying chiral carbon atoms
Notes
 identifying chiral carbon atoms
27.17.23UNa-d
Title
 p 1113-1e
Caption
 Ex. 37-identifying and naming functional groups
Notes
 identifying and naming functional groups
27.17.24UNa-d
Title
 p 1113-1f
Caption
 Ex. 38-identifying and naming functional groups
Notes
 identifying and naming functional groups
27.17.25UN
Title
 ??
Caption
 Ex. 47c-structures
Notes
 structures
27.17.26UNa-d
Title
 p 1114-1a
Caption
 Ex. 53-naming amines
Notes
 naming amines
27.17.27UNb-c
Title
 p 1114-1b
Caption
 Ex. 54-naming amines
Notes
 naming amines
27.17.28UN
Title
 p 1115-1a
Caption
 Ex. 60a-Marnikov's rule
Notes
 Marnikov's rule
27.17.29UN
Title
 p 1115-1b
Caption
 Ex. 61c-structures
Notes
 structures
27.17.30UN
Title
 p 1115-1c
Caption
 Ex. 62c-structures
Notes
 structures
27.17.31UN
Title
 ??
Caption
 Ex. 65c-reactions
Notes
 reactions
27.17.32UN
Title
 p 1115-1d
Caption
 Ex. 73-structures of reaction products
Notes
 structures of reaction products
27.17.33UN
Title
 p 1116-1a
Caption
 Ex. 74-structures of reaction products
Notes
 structures of reaction products
27.17.34UN
Title
 p 1116-1b
Caption
 Ex. 78a-structures of reaction products
Notes
 structures of reaction products
27.17.35UNa-c
Title
 p 1116-1c
Caption
 Ex. 79-structures of reaction products
Notes
 structures of reaction products
27.17.36UNa-c
Title
 p 1116-1d
Caption
 Ex. 80-structures of reaction products
Notes
 structures of reaction products
27.17.37UNa-f
Title
 p 1116-1e
Caption
 Ex. 81-identifying isomers, enetiomers, or identical molecules
Notes
 identifying isomers, enetiomers, or identical molecules
27.17.38UNa-f
Title
 p 1116-1f
Caption
 Ex. 82-identifying isomers, enetiomers, or identical molecules
Notes
 identifying isomers, enetiomers, or identical molecules
27.17.39UNa-d
Title
 p 1116-1g
Caption
 Ex. 83-dentifying isomers, enetiomers, or identical molecules
Notes
 identifying isomers, enetiomers, or identical molecules
27.17.40UNa-d
Title
 p 1117-1a
Caption
 Ex. 84-naming molecules
Notes
 naming molecules
27.17.41UNa-d
Title
 p 1117-1b
Caption
 Ex. 85-naming molecules
Notes
 naming molecules
27.17.42UNa-d
Title
 p 1117-1c
Caption
 Ex. 86-naming molecules
Notes
 naming molecules
27.17.43UN
Title
 p 1117-1d
Caption
 Ex. 90-SN1 reaction
Notes
 SN1 reaction
27.17.44UN
Title
 p 1118-1a
Caption
 Ex. 99-structure
Notes
 structures
27.17.45UN
Title
 p 1118-1b
Caption
 Ex. 105-structure
Notes
 structures
27.17.46UN
Title
 p 1118-1c
Caption
 Ex.106-structure
Notes
 structures
27.17.47UN
Title
 p 1119-1b
Caption
 Ex. 113-structure
Notes
 structures
27.17.48UNa-e
Title
 p 1119-1a
Caption
 Ex. 121-identifying systemic names
Notes
 identifying systemic names
27.17.49UN
Title
 p 1120-1a
Caption
 levomethadylacetate
Notes
 levomethadylacetate
27.17.50UN
Title
 p 1120-1b
Caption
 thiamphenicol
Notes
 thiamphenicol
27-17-51UN
Title
 p 1120-1c
Caption
 ephedrine
Notes
 ephedrine
27.17.52UN
Title
 p 1120-1d
Caption
 the Gringard regeant
Notes
 the Gringard regeant
Movie
Title
 p 1073-3
Caption
  
Notes
 Testing for unsaturated hydrocarbons with Bromine
Movie
Title
 p 1105-3
Caption
 Demonstration of the synthesis of nylon 610
Notes
 Synthesis of Nylon 610. Nylon 610 is a condensation polymer formed by the reaction of decanedioyl dichloride and 1,6-diaminohexane. The 1,6-diaminohexane is dissolved in a solution of NaOH and poured into a beaker containing decanedioyl dichloride. The reaction takes place at the interface between the two liquids. The nylon forms a string which can be pulled out of the solution. The reaction continues at the interface as the nylon is removed.
p 1081-1d
Title
 p 1081-1d
Caption
  
Notes
 Yellow orange crystals of PCC
Table 27.3
Title
 Table 27.3
Caption
  
Notes
 boiling points of some isomeric alkanes
Table 27.4
Title
 Table 27.4
Caption
  
Notes